Which of the following can form minimum boiling azeotrope mixture

Question: Which of the following can form minimum boiling azeotrope mixture

Option 1) HCI + H2O

Option 2) H2O + HNO3

Option 3)n-Hexane + n-Heptane

Option 4) H2O + C2H3OH

Answer: The correct answer is option 1 HCI + H2O

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